Willard Gibbs Quotes

His true monument lies not on the shelves of libraries, but in the thoughts of men, and in the history of more than one science. {Gibbs's obituary for scientist Rudolf Clausius}

Willard Gibbs did for statistical mechanics and for thermodynamics what Laplace did for celestial mechanics and Maxwell did for electrodynamics, namely, made his field a well-nigh finished theoretical structure.

One of the principal objects of theoretical research is to find the point of view from which the subject appears in the greatest simplicity.

In the last generation, this country produced one of the most eminent men of science in the whole world. His name was quite unknown among us while he lived, and it is still unknown. Yet I may say without too great exaggeration that when I heard it mentioned in a professional assembly in the Netherlands two years ago, everybody got down under the table and touched their foreheads to the floor. His name was Josiah Willard Gibbs.

Willard Gibbs is the type of the imagination at work in the world. His story is that of an opening up which has had its effect on our lives and our thinking; and, it seems to me, it is the emblem of the naked imagination —which is called abstract and impractical, but whose discoveries can be used by anyone who is interested, in whatever 'field'— an imagination which for me, more than that of any other figure in American thought, any poet, or political, or religious figure, stands for imagination at its essential points.

Qu'une goutee de vin tombe dans un verre d'eau; quelle que soit la loi du movement interne du liquide, nous verrons bientôt se colorer d'une teinte rose uniforme et à partir de ce moment on aura beau agiter le vase, le vin et l'eau ne partaîtront plus pouvoir se séparer. Tout cela, Maxwell et Boltzmann l'ont expliqué, mais celui qui l'a vu plus nettement, dans un livre trop peu lu parce qu'il est difficile à lire, c'est Gibbs dans ses principes de la Mécanique Statistique. Let a drop of wine fall into a glass of water; whatever be the law that governs the internal movement of the liquid, we will soon see it tint itself uniformly pink and from that moment on, however we may agitate the vessel, it appears that the wine and water can separate no more. All this, Maxwell and Boltzmann have explained, but the one who saw it in the cleanest way, in a book that is too little read because it is difficult to read, is Gibbs, in his Principles of Statistical Mechanics.

...only one man lived who could understand Gibbs's papers. That was Maxwell, and now he is dead.

Unassuming in manner, genial and kindly in his intercourse with his fellow-men, never showing impatience or irritation, devoid of personal ambition of the baser sort or of the slightest desire to exalt himself... In the minds of those who knew him, the greatness of his intellectual achievements will never overshadow the beauty and dignity of his life. [H.A. Burnstead's comments on the life of esteemed scientist J. Willard Gibbs]

Perplexed about entropy? You are not alone. Josiah Willard Gibbs (1839–1903) understood this confusion all too well, almost 150 years ago, “ . . . a method involving the notion of entropy, the very existence of which depends upon the second law of thermodynamics, will doubtless seem to many far-fetched, and may repel beginners as obscure and difficult of comprehension. This inconvenience is perhaps more than counter-balanced by the advantages of a method which makes the second law of thermodynamics so prominent, and gives it so clear and elementary an expression. . . . (1).” Gibbs profoundly altered our understanding of chemistry with his insights. At a time when it was mostly a philosophical concept, Gibbs went straight for application and made entropy relevant. Rapid advancements and heralded achievements in the chemical sciences ensued. Enthalpy (H) is a measure of the internal energy of a system, but this energy has an availability issue; some of that energy is useful, some is not. Enthalpy also provides no information about the spontaneity of energy exchange. Entropy (S) does indicate the probability of energy exchange (i.e., spontaneous, −∆S, or nonspontaneous, +∆S), but it is not useful energy and so it provides little information on the quantity of energy that is available to perform work. Energy that is available to perform useful work is known as Gibbs energy, symbolized as G. Gibbs energy has also been termed free energy. Yet energy is anything but “free” and so that term will not be used here

This irrelevance of molecular arrangements for macroscopic results has given rise to the tendency to confine physics and chemistry to the study of homogeneous systems as well as homogeneous classes. In statistical mechanics a great deal of labor is in fact spent on showing that homogeneous systems and homogeneous classes are closely related and to a considerable extent interchangeable concepts of theoretical analysis (Gibbs theory). Naturally, this is not an accident. The methods of physics and chemistry are ideally suited for dealing with homogeneous classes with their interchangeable components. But experience shows that the objects of biology are radically inhomogeneous both as systems (structurally) and as classes (generically). Therefore, the method of biology and, consequently, its results will differ widely from the method and results of physical science.

To prove to an indignant questioner on the spur of the moment that the work I do was useful seemed a thankless task and I gave it up. I turned to him with a smile and finished, 'To tell you the truth we don't do it because it is useful but because it's amusing.' The answer was thought of and given in a moment: it came from deep down in my mind, and the results were as admirable from my point of view as unexpected. My audience was clearly on my side. Prolonged and hearty applause greeted my confession. My questioner retired shaking his head over my wickedness and the newspapers next day, with obvious approval, came out with headlines 'Scientist Does It Because It's Amusing!' And if that is not the best reason why a scientist should do his work, I want to know what is. Would it be any good to ask a mother what practical use her baby is? That, as I say, was the first evening I ever spent in the United States and from that moment I felt at home. I realised that all talk about science purely for its practical and wealth-producing results is as idle in this country as in England. Practical results will follow right enough. No real knowledge is sterile. The most useless investigation may prove to have the most startling practical importance: Wireless telegraphy might not yet have come if Clerk Maxwell had been drawn away from his obviously 'useless' equations to do something of more practical importance. Large branches of chemistry would have remained obscure had Willard Gibbs not spent his time at mathematical calculations which only about two men of his generation could understand. With this trust in the ultimate usefulness of all real knowledge a man may proceed to devote himself to a study of first causes without apology, and without hope of immediate return.

Demolishes your demons, even if they are as fearsome as that of James Clerk Maxwell, remember that just as Josiah Willard Gibbs turned to his angel, you too will not be in science alone".

As entropy increases, the universe, and all closed systems in the universe, tend naturally to deteriorate and lose their distinctiveness, to move from the least to the most probable state, from a state of organization and differentiation in which distinctions and forms exist, to a state of chaos and sameness. In [Josiah Willard] Gibbs’ universe order is least probable, chaos most probable. But while the universe as a whole, tends to run down, there are local enclaves of whose direction seems opposed to that of the universe at large and in which there is a limited and temporary tendency for organization to increase. Life finds its home in these enclaves. It is with this point of view at its core that the new science of Cybernetics began its development.

Because the formula he derived for measuring the average number of bits needed to encode a piece of information looked almost exactly like Ludwig Boltzmann and Josiah Willard Gibbs’s formula for calculating entropy in thermodynamics. Here’s Shannon’s equation for calculating the size of any given piece of information: H = –Σi pi logb pi And here’s one way of stating Boltzmann’s equation for calculating the entropy of any given system: S = –kB Σi pi ln pi These two equations don’t just look similar; they’re effectively the same. Shortly after deriving his equation, Shannon pointed the similarity out to John von Neumann, then widely considered the world’s best mathematician. Von Neumann shrugged, suggesting that Shannon call his measure of the number of bits needed to carry a piece of information information entropy on the grounds that no one really understood thermodynamic entropy either.